Año 2012

• Multiple Carbon-Carbon and Carbon-Metal Bond Formation from an Iridium-pybox Complex and Electron-Poor Terminal Alkynes: Synthesis of Iridium Complexes with a Novel k4-(N,N,N,C) Tetradentate Ligand. Paredes, P.; Vega E.; Díez J.; Gamasa, M. P. Organometallics, 2012, 31, 3798.

• Synthesis and Structural Characterization of Pincer Pyridine Diphosphite Complexes of Rhodium and Iridium. Rubio, M.; Suárez, A.; Vega, E.; Álvarez, E.; Díez, J.; Gamasa, M. P.; Pizzano, A. European Journal of Inorganic Chemistry, 2012, 2012, 655-663.

2011

• Reactivity of dinuclear copper(I)/pybox complexes towards isocyanides and phosphanes. M. Panera, J. Díez, I. Merino, E. Rubio, M. P. Gamasa, Eur. J. Inorg. Chem., 2011, 393-404.

• Mononuclear ruthenium(II) complexes bearing the (S,S)-ⁱPr-pybox ligand. D. Cuervo, E. Menéndez-Pedregal, J. Díez, M. P. Gamasa, J. Organomet. Chem., 2011, 696, 1861-1867.

• Novel rhenium(I) catalysts for the isomerization of propargylic alcohols into a,b-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids. J. García-Álvarez, J. Díez, J. Gimeno, C. M. Seifried, Chem. Commun., 2011, 47, 6470-6472.

• Synthesis and structure of ruthenium(IV) complexes featuring N-heterocyclic ligands with an N-H group as the hydrogen-bond donor: hydrogen interactions in solution and in the solid state. J. Díez, J. Gimeno, I. Merino, E. Rubio, F. J. Suárez, Inorg. Chem., 2011, 50, 4868-4881.

• Access to unusual polycyclic spiro enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence. E. Piedra, J. Francos, N. Nebra, F. J. Suárez, J. Díez, V. Cadierno, Chem. Commun., 2011, 47, 7866-7868.

• Conjugate addition of arylboronic acids to a,b-unsaturated carbonyl compounds in aqueous medium using Pd(II) complexes with dihydroxy-2,2'-bipyridine ligands: homogeneous or heterogeneous nano-catalysis? E. Tomás-Mendivil, J. Díez, V. Cadierno, Catal. Sci. Technol., 2011, in press.

• Expeditious entry to novel 2-methylene-2,3-dihydrofuro[3,2-c]chromen-2-ones from 6-chloro-4-hydroxychromen-2-one and propargylic alcohols. N. Nebra, A. E. Díaz-Álvarez, J. Díez, V. Cadierno, Molecules, 2011, 16, 6470-6480.

• Synthesis and structural features of new ruthenium(II) complexes containing the scorpionate ligands tris(pyrazol-1-yl)methanesulfonate (Tpms) and tris(pyrazol-1-yl)methane (Tpm). S. Miguel, J. Díez, M. P. Gamasa, E. Lastra, Eur. J. Inorg. Chem., 2011, 4745-4755.

• Ruthenium-mediated cyclometalation reactions of allene and allylphosphine C=C bonds: synthesis of k(P),n4-(Hexa-2,5-dien-1-yl)diphenylphosphine-Ruthenium(II) Complexes. k(P),h⁴-(hexa-2,5-dien-1-yl)diphenylphosphine-ruthenium complexes. A. Villar, J. Díez, E. Lastra, M. P. Gamasa, Organometallics, 2011, 30, 5803-5808.

2010

• Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph₂P(=Se)CH₂P(=NR)Ph₂: coordination of their methanide and methandiide anions to ruthenium. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Dalton Trans., 2010, 39, 941-956.

• Alkyne activation by half-sandwich ruthenium(II) complexes bearing the water-soluble phosphane 1,3,5-triaza-7-phosphaadamantane (PTA). A. García-Fernández, M. P. Gamasa, E. Lastra, J. Organomet. Chem., 2010, 695, 162-169.

• Novel push-pull butadienes derived from 1,1-diaryl-2-propyn-1-ols and 1,1,1,5,5,5-hexafluoro-2,4-pentanedione: synthesis, absorption spectral properties and solvatochromic behaviour. J. Borge, V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Dyes Pigm., 2010, 87, 209-217.

• Chiral phosphonite, phosphite and phosphoramidite h⁶-arene-ruthenium(II) complexes: application to kinetic resolution of allylic alcohols. M. A. Fernández-Zúmel, B. Lastra-Barreira, M. Scheele, J. Díez, P. Crochet, J. Gimeno, Dalton Trans., 2010, 39, 7780-7785.

• Bis(allyl)-ruthenium(IV) complexes containing water-soluble phosphane ligands: synthesis, structure and application as catalysts in the selective hydration of organonitriles into amides. V. Cadierno, J. Díez, J. Francos, J. Gimeno, Chem. Eur. J., 2010, 16, 9808-9817.

• Arene-ruthenium(II) complexes containing amino-phosphine ligands as catalysts for nitrile hydration reactions. R. García-Álvarez, J. Díez, P. Crochet, V. Cadierno, Organometallics, 2010, 29, 3955-3965.

• Antitumor activity of new hydrotris(pyrazolyl)borate ruthenium(II) complexes containing the phosphanes PTA and 1-CH₃-PTA. A. García-Fernández, J. Díez, A. Manteca, J. Sánchez, R. García-Navas, B. G. Sierra, F. Mollinedo, M. P. Gamasa, E. Lastra, Dalton Trans., 2010, 39, 10186-10196.

• Cationic rhodium(I)-diolefin complexes containing an optically active C₂-symmetric bis(sulfoximine) ligand: synthesis and catalytic activity. V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, A. Pizzano, Polyhedron, 2010, 29, 3380-3386.

• A highly copper(I) catalyst for the 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: regioselective synthesis of 1,4-disubstituted and 1,4,5-trisubstituted 1,2,3-triazoles. J. García-Álvarez, J. Díez, J. Gimeno, Green Chem., 2010, 12, 2127-2130.

• A simple, general route to 2-pyridylidene transition metal complexes. M. Roselló-Merino, J. Díez, S. Conejero, Chem. Commun., 2010, 46, 9247-9249.

2009

• Facile modification of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1^3,7]decane phosphanes coordinated to ruthenium(II). A. García-Fernández, J. Díez, M. P. Gamasa, E. Lastra, Inorg. Chem. 2009, 48, 2471-2481.

• Novel η¹-allyl- and acyliridium(III) / pybox complexes. P. Paredes, J. Díez, M. P. Gamasa, Polyhedron, 2009, 28, 57-62.

• Synthesis of copper(I) complexes containing enantiopure pybox ligands: first assays on enantioselective synthesis of propargylamines catalyzed by isolated copper(I) complexes. M. Panera, J. Díez, I. Merino. E. Rubio, M. P. Gamasa, Inorg. Chem., 2009, 48, 11147-11160.

• Highly water-soluble arene-ruthenium(II) complexes: application to catalytic isomerization of allylic alcohols in aqueous medium. B. Lastra-Barreira, J. Díez, P. Crochet, Green Chem., 2009, 11, 1681-1686.

2008

• (η⁶-Arene)-ruthenium(II) complexes containing methanide and methandiide anions of Ph₂P(=S)CH₂P(=NR)Ph₂: unprecedent insertion of isocyanide into a ruthenium-carbene bond. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2008, 27, 1809-1822.

• Novel hydridotris(pyrazoyl)borate ruthenium(II) complexes containing the water-soluble phosphane 1,3,5.triaza-7-phosphaadamantane: Synthesis and evaluation of DNA binding properties. A. García-Fernández, J. Díez, A. Manteca, J. Sánchez, M. P. Gamasa, E. Lastra, Polyhedron, 2008, 27, 1214-1228.

• Asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes bearing a chiral phosphinoferrocenyloxazoline ligand. C. A. Madrigal, A. García-Fernández, J. Gimeno, E. Lastra, J. Organomet. Chem., 2008, 693, 2535-2540.

• Ruthenium/TFA catalyzed coupling of activated secondary propargylic alcohols with cyclic 1,3-diones: furan vs pyran ring formation. V. Cadierno, J. Diez, J. Gimeno, N. Nebra, J. Org. Chem., 2008, 73, 5852-5858.

• Novel ruthenium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligand Ph₂PCH₂P{=NP(=O)(OEt)₂}Ph₂: a new coordination mode of its methanide anion. V. Cadierno, J. Diez, J. García-Álvarez, J. Gimeno, J. Rubio-García, Dalton Trans., 2008, 5737-5748.

• Alkene and alkyne insertion into the Ir-H bond: synthesis of the new mono- and dinuclear alkyl and alkenyl iridium-pybox complexes. P. Paredes, J. Diez, M. P. Gamasa, J. Organomet. Chem., 2008, 693, 3681-3687.

• Synthesis of enantiopure iridium(I) and iridium(III) pybox complexes and their application in the asymmetric transfer hydrogenation of ketones. P. Paredes, J. Díez, M. P. Gamasa, Organometallics, 2008, 27, 2597-2607.

2007

• Silver(I) complexes of N-thiophosphorylated bis(iminophosphorane) ligands: from monomers to polymers. V. Cadierno, J. Diez, J. García-Álvarez, J. Gimeno, Dalton Trans., 2007, 2760-2769.

• Half-sandwich h⁵-indenyl- and h⁶-areneruthenium(II) complexes bearing the chiral ligand (4S)-2[(Sp)-2-(diphenylphosphanyl)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). A. García-Fernández, J. Gimeno, E. Lastra, C. A. Madrigal, C. Graiff, A. Tiripicchio, Eur. J. Inorg. Chem., 2007, 732-741.

2006

• Tetra-, di- and mononuclear copper(I) complexes containing (S,S)-ⁱPr-pybox and (R,R)-Ph-pybox ligands. J. Díez, M. P. Gamasa, M. Panera, Inorg. Chem., 2006, 45, 10043-10045.

• Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph₂PCH₂P{=NP(=O)(OR)₂}Ph₂ (R = Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, N. Nebra, J. Rubio-García, Dalton Trans., 2006, 5593-5604.

• Efficient access to conjugated dienones and diene-diones from propargylic alcohols and enolizable ketones: a tandem isomerization/condensation process catalyzed by the sixteen-electron allyl-ruthenium(II) complex [Ru(η³-2-C₃H₄Me)(CO)(dppf)][SbF₆]. V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, N. Nebra, Adv. Synth. Catal., 2006, 348, 2125-2132.

• From alkenylphosphane aminoallenylidene ruthenium(II) complexes to highly unsaturated ruthenaphosphabicycloheptene complexes. J. Díez, M. P. Gamasa, J. Gimeno, E. Lastra, A. Villar, J. Organomet. Chem., 2006, 691, 4092-4099.

• Transfer hydrogenation of ketones catalysed by new half-sandwich ruthenium(II) complexes bearing the sulfonated phosphane (meta-sulfonatophenyl)diphenylphosphane potassium salt (TPPMS). J. Díez, M. P. Gamasa, E. Lastra, A. García Fernández, M. P. Tarazona, Eur. J. Inorg. Chem., 2006, 2855-2864.

• Rhodium(III) complexes containing the ligand 2,6-bis[(4’-(S)-isopropyloxazolin-2’-yl]pyridine ((S,S)-ⁱPr-pybox): efficient catalysts for asymmetric hydrosilylation of acetophenone. D. Cuervo, M. P. Gamasa, J. Gimeno, J. Mol. Catal. A: Chem., 2006, 249, 60-64.

• Novel carbonyliridium and -rhodium complexes containing 2,6-bis[(4’S)-4’-isopropyloxazolin-2’-yl]pyridine (ⁱPr-pybox) and 2,6-bis[(4’R)-4’-phenyloxazolin-2’-yl]pyridine (Ph-pybox) ligands. D. Cuervo, J. Díez, M. P. Gamasa, J. Gimeno, P. Paredes, Eur. J. Inorg. Chem., 2006, 599-608.

• Synthesis of new half-sandwich ruthenium(II) complexes bearing alkenyl- and alkynylphosphane ligands. J. Díez, M. P. Gamasa, J. Gimeno, E. Lastra, A. Villar, Eur. J. Inorg. Chem., 2006, 78-87.

• Catalytic isomerization of allylic alcohols by (h⁶-p-cymene)-ruthenium(II) complexes in organic and aqueous media: new recyclable and highly efficient catalysts in water containing ammonium-functionalized ligands. P. Crochet, J. Díez, M. A. Fernández-Zúmel, J. Gimeno, Adv. Synth. Catal., 2006, 348, 93-100.

2005

• Efficient one-pot synthesis of a,b-unsaturated carbyne complexes fac-[RuX₃{≡CC(H)=CR₂}(dppf)] (X = Cl, Br; R = aryl, alkyl; dppf = 1,1'-bis(diphenylphosphino)ferrocene). V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics, 2005, 24, 3111-3117.

• Iminophosphorane-based nucleophilic ruthenium(II) carbene complexes: unusual C-C coupling and C-H activation promoted by the addition of alkynes to the Ru=C bond. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2005, 24, 2801-2810.

• One-pot stereoselective synthesis of organorhodium(III) complexes containing the chiral ligand 2,6-bis[4’-(S)-isopropyloxazolin-2’-yl]pyridine (ⁱPr-pybox). D. Cuervo, J. Díez, M. P. Gamasa, J. Gimeno, Organometallics, 2005, 24, 2224-2232.

• Novel (h⁶-arene)-ruthenium(II) complexes containing bis(iminophosphorano)methanide and methandiide ligands. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, J. Organomet. Chem., 2005, 690, 2087-2096.

• Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: synthesis and reactivity of the diolefin iridium(I) complex [Ir(²-C₂H₄)₂{³N,N,N-(S,S)-i-Pr-pybox}][PF₆] ((S,S)-i-Pr-pybox = 2,6-bis(4'-(S)-isopropyloxazolin-2'-yl)pyridine). J. Díez, M. P. Gamasa, J. Gimeno, P. Paredes, Organometallics, 2005, 24, 1799-1802.

• Intramolecular [2+2] cycloaddition of allyl C=C and allenylidene Ca=Cb bonds: formation and deprotonation of cyclobutylidene rings. J. Díez, M. P. Gamasa, E. Lastra, J. Gimeno, A. Villar, Organometallics, 2005, 24, 1410-1418.

2004

• Indenyl ruthenium(II) aminoallenylidenes: a new building-block for the synthesis of highly unsaturated alkynyl and allenylidene complexes. S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, Organometallics, 2004, 23, 6299-6310.

• Base-assisted cyclometalation and phosphorus-carbon bond cleavage in (arene)ruthenium(II) complexes containing functionalized iminophosphorane-phosphine ligands Ph₂PCH₂P{=NP(=X)(OR)₂}Ph₂ (X = O, S; R = Et, Ph). V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2004, 23, 3425-3436.

• Five- and six-coordinate ruthenium(II) complexes containing the bidentate phosphine (-)-N,N-bis(diphenylphosphino)-(S)-1-phenylethylamine [(S)-peap]: X-ray crystal structure of the first 16 electron ruthenium complex bearing a four membered ring [RuCl{k²-P,P-(S)-peap}₂][SbF₆]·C₂H₄Cl₂. J. Díez, M. P. Gamasa, J. Gimeno, Y. Rodríguez, S. García-Granda, Eur. J. Inorg. Chem., 2004, 2078-2085.

• Diastereoselective synthesis of the indenylruthenium(II) complexes [Ru(h⁵-C₉H₇){k³(P,C,C)-Ph₂P(CH₂CR=CH₂)}(PPh₃)][PF₆] (R = H, Me): enantiofacial coordination, hemilabile properties, and diastereoselective nucleophilic additions to k³(P,C,C)-allylphosphine ligands. P. Álvarez, E. Lastra, J. Gimeno, P. Braña, J. A. Sordo, J. Gómez, L. R. Falvello, M. Bassetti, Organometallics, 2004, 23, 2956-2966.

• A new class of tethered-arene ruthenium(II) complexes with pendant P and C donor atoms: synthesis of η⁶:η¹:η¹ phosphonio-azabutadienyl ruthenabicycles via allenylidene intermediates. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Chem. Commun., 2004, 1820-1821.

• New chiral ruthenium(II) catalysts containing 2,6-bis(4'-(R)-phenyloxazolin-2'-yl)pyridine (Ph-pybox) ligands for highly enantioselective transfer hydrogenation of ketones. D. Cuervo, M. P. Gamasa, J. Gimeno, Chem. Eur. J., 2004, 10, 425-432.

• Bis(iminophosphorano)methane derivatives as precursors of unusual ruthenium-carbene complexes: a synthetic and DFT study. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2004, 23, 2421-2433.

• Reaction of the ruthenium(II) indenyl complex [Ru(h⁵-C₉H₇){k³(P,C,C)-PPh₂(CH₂CH=CH₂)}(PPh₃)][PF₆] with terminal alkynes. Mechanisms of 1-alkyne to h¹-vinylidene transformation and kinetic detection of hemilability of the allylphosphine ligand. M. Bassetti, P. Álvarez, J. Gimeno, E. Lastra, Organometallics, 2004, 23, 5127-5134.

• Efficient transfer hydrogenation of ketones catalyzed by the bis(isocyanide)-ruthenium(II) complexes trans,cis,cis-[RuX₂(CNR)₂(dppf)] (X = Cl, Br; dppf = 1,1'-bis(diphenylphosphino)ferrocene): isolation of active mono- and dihydride intermediates. V. Cadierno, P, Crochet, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics, 2004, 23, 4836-4845.

• [Ru(h³-2-C₃H₄Me)(CO)(dppf)][SbF₆]: a mononuclear 16 e^- ruthenium(II) catalyst for propargylic substitution and isomerization of HC≡CCPh₂(OH). V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Chem. Commun., 2004, 2716-2717.

2003

• An easy entry to dimers [{RuX(m-X)(CO)(P^P)}₂] (X = Cl; Br; P^P = 1,1'-bis(diphenylphosphino)ferrocene, 1,1'-bis(diisopropylphosphino)ferrocene) from h³-allyl-ruthenium(II) derivatives [RuX(h³-2-C₃H₄R)(CO)(P^P)] (R = H, Me): efficient catalyst precursors in transfer hydrogenation of ketones. V. Cadierno, P. Crochet, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics, 2003, 22, 5226-5234.

• Synthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(II) and ruthenium(IV) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph₂PCH₂P{=NP(=S)(OR)₂}Ph₂ (R = Et, Ph). V. Cadierno, P. Crochet, J. Díez, J. García-Álvarez, S. E. García-Garrido, S. García-Granda, J. Gimeno,  M. A. Rodriguez, J. Chem. Soc., Dalton Trans., 2003, 3240-3249.

• Indenyl-ruthenium(II) allenylidene complexes containing terpenic substituents as precursors of optically active terminal alkynes: scope and limitation. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, J. Chem. Soc., Dalton Trans., 2003, 3060-3066.

• Formation of a cyclobutylidene ring: intramolecular [2+2] cycloaddition of allyl and vinylidene C=C bonds under mild conditions. P. Álvarez, E.  Lastra, J. Gimeno, M. Bassetti, L. R. Falvello, J. Am. Chem. Soc., 2003, 125, 2386-2387.

• Unexpected coupling between an h⁵-indenyl ligand and alkenylvinylidene fragments: synthesis of unprecedented (h⁶-indene)ruthenium(II) metallacycles. V. Cadierno, S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, S. García-Granda, Chem. Comm., 2003, 840-841.

• Synthesis of indenyl-ruthenium(II) s–alkynyl complexes via nucleophilic addition of the (1R)-(+)- and (1S)-(-)-camphor enolates on the allenylidene group of [Ru(=C=C=CPh₂)(h⁵-C₉H₇)(PPh₃)₂][PF₆]: efficient synthesis of novel optically pure vinylidene derivatives. V. Cadierno, M. P. Gamasa, J. Gimeno, E. Pérez-Carreño, S. García-Granda, J. Organomet. Chem., 2003, 670, 75-83.

• h⁵-Indenylruthenium(II) hydride complexes: synthesis and protonation reactions. M. P. Gamasa, J. Gimeno, C. González-Bernardo, B. M. Martín-Vaca, J. Borge, S. García-Granda, Inorg. Chim. Acta, 2003, 347, 181-188.

• Novel indenyl half-sandwich osmium(II) complexes. X-ray structure of [Os{=C=C(H)Bu^t}(h⁵-C₉H₇)(PPh₃)₂][PF₆]^.OEt₂. J. Gimeno, M. González-Cueva, E. Lastra, E. Pérez-Carreño, S. García-Granda, Inorg. Chim. Acta, 2003, 347, 99-106.

• Ruthenium(II) and ruthenium(IV) complexes containing k¹-P-,k²-P,O- and k³-P,N,O-iminophosphorane-phosphine ligands Ph₂PCH₂P{=NP(=O)(OR)₂}Ph₂ (R = Et, Ph): synthesis, reactivity, theoretical studies and catalytic activity in transfer hydrogenation of cyclohexanone. V. Cadierno, P. Crochet, J. Díez, J. García-Álvarez, S. E. García-Garrido, J. Gimeno, Inorg. Chem., 2003, 42, 3293-3307.

2002

• New ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). X-ray structures of mer,trans-[RuCl₂(dppm)(FcPN)] (dppm = bis(diphenylphosphino)methane) and cis-[RuCl₂(CO)(py)(FcPN)]. J. Gimeno, E. Lastra, C. Madrigal, C. Graiff, A. Tiripicchio, J. Organomet. Chem., 2002, 663, 204-212.

• Synthesis and properties of the indenyl ruthenium(II) complex [Ru(E)-h¹-C(C≡CPh)=CHPh)(h⁵-C₉H₇)(k²-P,P-dppm)] (dppm = bis(diphenylphoshino)methane. An organometallic intermediate in the catalytic dimerization of phenylacetylene. M. Bassetti, S. Marini, J. Díez, M. P. Gamasa, J. Gimeno, Y. Rodríguez-Álvarez, S. García-Granda, Organometallics, 2002, 21, 4815-4822.

• Catalytic synthesis of polynorbornene and polynorbornadiene of low polydispersity index by [Ru(h⁵-C₉H₇)Cl(COD)] (COD = 1,5-cyclooctadiene). P. Álvarez, J. Gimeno, E. Lastra, Organometallics, 2002, 21, 5678-5680.

• Rhodium(I) and rhodium(III) complexes containing the chiral ligand 2,6-bis[4'(S)-ⁱPr-oxazolin-2'-yl]pyridine (pybox): an unprecedented monohapto coordination of pybox. D. Cuervo, J. Díez, M. P. Gamasa, S. García-Granda, J. Gimeno, Inorg. Chem., 2002, 41, 4999-5001.

• Generation of polyunsaturated cumulene chains by unprecedented insertions of the ynamine MeC≡CNEt₂ in ruthenium(II) allenylidene complexes. S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, S. García-Granda, Angew. Chem. Int. Ed., 2002, 41, 3439-3442.

• Synthesis and characterization of 2-oxacycloalkylideneruthenium(II) complexes: X-ray crystal structure of the 2-oxacycloheptylidene complex [Ru{=COCH₂(CH₂)₃CH₂}(h⁵-C₉H₇)(PPh₃)₂][PF₆]·CH₂Cl₂. M. P. Gamasa, J. Gimeno, B. M. Martín-Vaca, R. Isea, A. Vegas, J. Organomet. Chem., 2002, 651, 22-33.

• (Alkenylalkylidene)(indenyl)ruthenium(II) complexes: synthesis by protonation of alkenyl derivatives. K. Bieger, J. Díez, M. P. Gamasa, J. Gimeno, M. Pavlista, Y. Rodríguez-Álvarez, S. García-Granda, R. Santiago-García, Eur. J. Inorg. Chem., 2002, 1647-1656.

• Easy entry to terminal 1,5- and 1,6-enynes from (indenyl)ruthenium(II) allenylidenes and Grignard reagents. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, Organometallics, 2002, 21, 3837-3840.

• In search of optically active g-keto acetylenes via regioselective coupling of allenylidene groups and cyclic enolates. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, L. R. Falvello, R. M. Llusar, Organometallics, 2002, 21, 3716-3726.

• Ruthenium(II) and ruthenium(IV) complexes containing hemilabile heterodifunctional iminophosphorane-phosphine ligands Ph₂PCH₂P(=NR)Ph₂. V. Cadierno, J. Díez, S. E. García-Garrido, S. García-Granda, J. Gimeno, J. Chem. Soc., Dalton Trans., 2002, 1465-1472.

• Activation of propargylic alcohols derived from hormonal steroids by the indenyl-ruthenium(II) complex [RuCl(h⁵-C₉H₇)(PPh₃)₂]: experimental and theoretical evidence of an allenylidene-vinylvinylidene equilibrium. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, M. A. Rodríguez, Organometallics, 2002, 21, 203-209.

2001

• Synthesis and electrochemical and theoretical studies of Fischer-type alkenyl-carbyne tungsten complexes [(dppe)(CO)₂(RNC)W{≡CCH=CCH₂CH₂(CH₂)_nCH₂}][BF₄] (R = Alkyl, Aryl). L. Zhang, M. F. C. Guedes da Silva, M. L. Kuznetsov, M. P. Gamasa, J. Gimeno, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, Organometallics, 2001, 20, 2782-2793.

• Octahedral ruthenium (II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). X-ray crystal structures of fac-[RuCl₂(PMe₃)₂(FcPN)] and fac-[RuCl₂(dppm)(FcPN)] (dppm = bis(diphenylphosphino)methane). J. Gimeno, E. Lastra, C. Madrigal, C. Graiff, A. Tiripicchio, J. Organomet. Chem., 2001, 637-639, 463-468.

• Copper(I) complexes containing 1,1'-bis(diphenylphosphino)ferrocene (dppf) as chelate ligand. X-ray crystal structures of [Cu₂(m-Cl)₂(k²-P,P-dppf)₂] and [Cu(CN^tBu)₂(k²-P,P-dppf)][BF₄]. J. Díez, P. Gamasa, J. Gimeno, M. Lanfranchi, A.Tiripicchio, J. Organomet. Chem., 2001, 637-639, 677-682.

• Synthesis and reactivity of indenyl ruthenium(II) complexes containing the labile ligand 1,5-cyclooctadiene (COD): catalytic activity of  [Ru(h⁵-C₉H₇)Cl(COD)]. P. Álvarez, J. Gimeno, E. Lastra, S. García-Granda, J. F. Van der Maelen,  M. Bassetti, Organometallics, 2001, 20, 3762-3771.

• Reactivity of indenyl-ruthenium(II) vinylidene complexes: selective synthesis of alkenyl-phosphonio derivatives via nucleophilic addition of triphenylphosphine on their h²-alkyne tautomers. Theoretical study of the h¹-vinylidene-h²-alkyne tautomerization. V. Cadierno, M. P. Gamasa, J. Gimeno, C. González-Bernardo, E. Pérez-Carreño, S. García-Granda, Organometallics, 2001, 20, 5177-5188.

• Efficient synthetic routes to terminal g–keto-alkynes and unsaturated cyclic carbene complexes based on regio- and diastereoselective nucleophilic additions of enolates on ruthenium(II) indenyl allenylidenes. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, E. Pérez-Carreño, S. García-Granda, Organometallics, 2001, 20, 3175-3189.

• Stereoselective synthesis of chiral terminal (E)-1,3-enynes derived from the aldehydes (1R)-(-)-myrtenal and (S)-(-)-perillaldehyde using the alkynyl-phosphonio complex [Ru{C≡CCH₂(PPh₃)}(h⁵-C₉H₇)(PPh₃)₂][PF₆] as synthon. V. Cadierno, M. P. Gamasa, J. Gimeno, J. Organomet. Chem., 2001, 621, 39-45.

• Intramolecular carbon-carbon coupling reactions of a k²(P,P)-bis(diphenylphosphino)methanide ligand with unsaturated carbene moieties in indenyl-ruthenium(II) complexes. V. Cadierno, M. P. Gamasa, J. Gimeno, B. M. Martín-Vaca, J. Organomet. Chem., 2001, 617-618, 261-268.

2000

• Synthesis, structural characterisation and electrochemical studies of neutral alkenylcarbyne tungsten complexes bearing chelating bidentate and tridentate phosphanes. L. Zhang, M. P. Gamasa, J. Gimeno, M. F. C. Guedes da Silva, A. J. L. Pombeiro, C. Graiff, M. Lanfranchi, A. Tiripicchio, Eur. J. Inorg. Chem., 2000, 1707-1715.

• Mono and dinuclear tungsten alkenyl-carbyne complexes bridged by cyanide and diisocyanide ligands: synthesis, electrochemical- and ¹⁸³W-NMR studies. L. Zhang, M. P. Gamasa, J. Gimeno, R. J. Carbajo, F. López-Ortiz, M. F. Guedes da Silva, A. J. L. Pombeiro, Eur. J. Inorg. Chem., 2000, 341-350.

• Nucleophilic additions of anionic Group 6 carbene complexes on cationic indenyl-ruthenium(II) allenylidene derivatives: an easy entry to bimetallic complexes containing s–alkynyl-carbene and vinylidene-carbene bridges. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, J. Chem. Soc., Dalton Trans., 2000, 451-457.

• Dimerization of terminal alkynes catalyzed by indenyl ruthenium(II) complexes. M. Bassetti, S. Marini, F. Tortorella, V. Cadierno, J. Díez, M. P. Gamasa, J. Gimeno, J. Organomet. Chem., 2000, 593-594, 292-298.

Reviews

• Synthesis and reactivity of a,b-unsaturated alkylidene and cumulenylidene group 8 half sandwich complexes. V. Cadierno, M. P. Gamasa, J. Gimeno, Coord. Chem. Rev., 2004, 248, 1627-1657.

• Recent developments in the reactivity of allenylidene and cumulenylidene complexes. V. Cadierno, M. P. Gamasa, J. Gimeno, Eur. J. Inorg. Chem., 2001, 571-591.

Book Chapters

In search of asymmetric propargylic substitution reactions mediated by optically active indenyl-ruthenium(II) allenylidene complexes, in Perspectives in Organometallic Chemistry.

Authors: V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno

Editorial: RSC Editions (Eds. C. G. Screttas, B. R. Steele)

Year: 2003

Pages: 285-296

ISBN: 0-85404-876-6