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Last update: March, 2013 |
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![Book chapters](images/button4.jpg) |
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Articles |
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![2007](images/button1F.jpg) |
![2012](images/button1C4.jpg) |
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Año 2012
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Multiple Carbon-Carbon and Carbon-Metal Bond Formation from an Iridium-pybox Complex and Electron-Poor Terminal Alkynes: Synthesis of Iridium Complexes with a Novel k4-(N,N,N,C) Tetradentate Ligand. Paredes, P.; Vega E.; Díez J.; Gamasa, M. P.
Organometallics, 2012, 31,
3798.
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Synthesis and Structural Characterization of Pincer Pyridine Diphosphite Complexes of Rhodium and Iridium. Rubio, M.; Suárez, A.; Vega, E.; Álvarez, E.; Díez, J.; Gamasa, M. P.; Pizzano, A.
European Journal of Inorganic Chemistry, 2012, 2012, 655-663.
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2011
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Reactivity of dinuclear copper(I)/pybox complexes towards
isocyanides and phosphanes. M. Panera, J. Díez, I. Merino, E.
Rubio, M. P. Gamasa, Eur. J. Inorg. Chem., 2011,
393-404.
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Mononuclear ruthenium(II) complexes bearing the (S,S)-iPr-pybox
ligand. D. Cuervo, E. Menéndez-Pedregal, J. Díez, M. P. Gamasa,
J. Organomet. Chem., 2011, 696, 1861-1867.
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Novel rhenium(I) catalysts for the isomerization of propargylic
alcohols into a,b-unsaturated
carbonyl compounds: an unprecedented recyclable catalytic system in
ionic liquids. J.
García-Álvarez, J. Díez, J. Gimeno, C. M. Seifried, Chem. Commun.,
2011, 47, 6470-6472.
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Synthesis and structure of ruthenium(IV) complexes featuring
N-heterocyclic ligands with an N-H group as the hydrogen-bond donor:
hydrogen interactions in solution and in the solid state. J.
Díez, J. Gimeno, I. Merino, E. Rubio, F. J. Suárez, Inorg. Chem.,
2011, 50, 4868-4881.
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Access to unusual polycyclic spiro enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls
using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen
sequence. E. Piedra, J. Francos, N. Nebra, F. J. Suárez, J. Díez,
V. Cadierno, Chem. Commun., 2011, 47, 7866-7868.
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Conjugate addition of arylboronic acids to
a,b-unsaturated
carbonyl compounds in aqueous medium using Pd(II) complexes with
dihydroxy-2,2'-bipyridine ligands: homogeneous or heterogeneous nano-catalysis?
E. Tomás-Mendivil, J. Díez, V. Cadierno, Catal. Sci. Technol.,
2011, in press.
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Expeditious entry to novel
2-methylene-2,3-dihydrofuro[3,2-c]chromen-2-ones from
6-chloro-4-hydroxychromen-2-one and propargylic alcohols. N.
Nebra, A. E. Díaz-Álvarez, J. Díez, V. Cadierno, Molecules,
2011, 16, 6470-6480.
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Synthesis and structural features of new ruthenium(II) complexes
containing the scorpionate ligands
tris(pyrazol-1-yl)methanesulfonate (Tpms) and
tris(pyrazol-1-yl)methane (Tpm). S. Miguel, J. Díez, M. P.
Gamasa, E. Lastra, Eur. J. Inorg. Chem., 2011,
4745-4755.
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Ruthenium-mediated cyclometalation
reactions of allene and allylphosphine C=C bonds: synthesis of k(P),n4-(Hexa-2,5-dien-1-yl)diphenylphosphine-Ruthenium(II) Complexes.
k(P),h4-(hexa-2,5-dien-1-yl)diphenylphosphine-ruthenium
complexes. A. Villar, J.
Díez, E. Lastra, M. P. Gamasa, Organometallics, 2011, 30,
5803-5808.
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2010
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Access to the first
(iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(=Se)CH2P(=NR)Ph2:
coordination of their methanide and methandiide anions to ruthenium.
V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Dalton Trans.,
2010, 39, 941-956.
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Alkyne activation
by half-sandwich ruthenium(II) complexes bearing the water-soluble
phosphane 1,3,5-triaza-7-phosphaadamantane (PTA). A. García-Fernández, M. P. Gamasa, E. Lastra,
J. Organomet. Chem., 2010, 695, 162-169.
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Novel push-pull butadienes derived from 1,1-diaryl-2-propyn-1-ols
and 1,1,1,5,5,5-hexafluoro-2,4-pentanedione: synthesis, absorption
spectral properties and solvatochromic behaviour. J. Borge, V.
Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Dyes Pigm.,
2010, 87, 209-217.
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Chiral phosphonite, phosphite and
phosphoramidite h6-arene-ruthenium(II)
complexes: application to kinetic resolution of allylic alcohols.
M. A. Fernández-Zúmel, B. Lastra-Barreira, M. Scheele, J. Díez, P.
Crochet, J. Gimeno, Dalton Trans., 2010, 39,
7780-7785.
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Bis(allyl)-ruthenium(IV) complexes containing water-soluble
phosphane ligands: synthesis, structure and application as catalysts
in the selective hydration of organonitriles into amides. V.
Cadierno, J. Díez, J. Francos, J. Gimeno, Chem. Eur. J., 2010,
16, 9808-9817.
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Arene-ruthenium(II) complexes containing amino-phosphine ligands
as catalysts for nitrile hydration reactions. R. García-Álvarez,
J. Díez, P. Crochet, V. Cadierno, Organometallics, 2010,
29, 3955-3965.
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Antitumor activity of new hydrotris(pyrazolyl)borate ruthenium(II)
complexes containing the phosphanes PTA and 1-CH3-PTA.
A. García-Fernández, J. Díez, A. Manteca, J. Sánchez, R.
García-Navas, B. G. Sierra, F. Mollinedo, M. P. Gamasa, E. Lastra,
Dalton Trans., 2010, 39, 10186-10196.
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Cationic rhodium(I)-diolefin complexes containing an optically
active C2-symmetric bis(sulfoximine) ligand:
synthesis and catalytic activity. V. Cadierno, J. Díez, S. E.
García-Garrido, J. Gimeno, A. Pizzano, Polyhedron, 2010,
29, 3380-3386.
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A highly copper(I) catalyst for the 1,3-dipolar cycloaddition of
azides with terminal and 1-iodoalkynes in water: regioselective
synthesis of 1,4-disubstituted and 1,4,5-trisubstituted
1,2,3-triazoles. J. García-Álvarez, J. Díez, J. Gimeno, Green
Chem., 2010, 12, 2127-2130.
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A simple, general route to 2-pyridylidene transition metal
complexes. M. Roselló-Merino, J. Díez, S. Conejero, Chem.
Commun., 2010, 46, 9247-9249.
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2009
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Facile modification of 1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane
phosphanes coordinated to ruthenium(II). A. García-Fernández, J. Díez, M. P. Gamasa, E. Lastra, Inorg. Chem. 2009, 48,
2471-2481.
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Novel η1-allyl- and acyliridium(III) /
pybox complexes. P. Paredes, J. Díez, M. P. Gamasa,
Polyhedron, 2009, 28, 57-62.
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Synthesis of copper(I) complexes containing enantiopure pybox
ligands: first assays on enantioselective synthesis of
propargylamines catalyzed by isolated copper(I) complexes. M. Panera,
J. Díez, I. Merino. E. Rubio, M. P. Gamasa, Inorg. Chem., 2009,
48, 11147-11160.
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Highly water-soluble arene-ruthenium(II) complexes: application to
catalytic isomerization of allylic alcohols in aqueous medium. B. Lastra-Barreira, J. Díez, P. Crochet,
Green Chem., 2009,
11, 1681-1686.
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2008
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(η6-Arene)-ruthenium(II)
complexes containing methanide and methandiide anions of Ph2P(=S)CH2P(=NR)Ph2:
unprecedent insertion of isocyanide into a ruthenium-carbene bond.
V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno,
Organometallics, 2008, 27, 1809-1822.
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Novel hydridotris(pyrazoyl)borate ruthenium(II)
complexes containing the water-soluble phosphane 1,3,5.triaza-7-phosphaadamantane:
Synthesis and evaluation of DNA binding properties. A.
García-Fernández, J. Díez, A. Manteca, J. Sánchez, M. P. Gamasa, E.
Lastra, Polyhedron, 2008, 27, 1214-1228.
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Asymmetric transfer hydrogenation of ketones
catalyzed by ruthenium(II) complexes bearing a chiral
phosphinoferrocenyloxazoline ligand. C. A. Madrigal, A.
García-Fernández, J. Gimeno, E. Lastra, J. Organomet. Chem.,
2008, 693, 2535-2540.
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Ruthenium/TFA catalyzed coupling of activated
secondary propargylic alcohols with cyclic 1,3-diones: furan vs
pyran ring formation. V. Cadierno, J. Diez, J. Gimeno, N. Nebra,
J. Org. Chem., 2008, 73, 5852-5858.
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Novel ruthenium(II) complexes
containing the N-phosphorylated iminophosphorane-phosphine ligand Ph2PCH2P{=NP(=O)(OEt)2}Ph2:
a new coordination mode of its methanide anion. V. Cadierno, J.
Diez, J. García-Álvarez, J. Gimeno, J. Rubio-García, Dalton Trans.,
2008, 5737-5748.
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Alkene and alkyne insertion into
the Ir-H bond: synthesis of the new mono- and dinuclear alkyl and
alkenyl iridium-pybox complexes. P. Paredes, J. Diez, M. P. Gamasa,
J. Organomet. Chem., 2008, 693, 3681-3687.
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Synthesis of enantiopure iridium(I)
and iridium(III) pybox complexes and their application in the
asymmetric transfer hydrogenation of ketones. P. Paredes, J. Díez,
M. P. Gamasa, Organometallics, 2008, 27,
2597-2607.
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2007
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Silver(I) complexes of N-thiophosphorylated bis(iminophosphorane) ligands:
from monomers to polymers. V. Cadierno, J. Diez, J.
García-Álvarez, J. Gimeno, Dalton Trans., 2007,
2760-2769.
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Half-sandwich
h5-indenyl-
and
h6-areneruthenium(II)
complexes bearing the chiral ligand
(4S)-2[(Sp)-2-(diphenylphosphanyl)ferrocenyl]-4-(methylethyl)oxazoline
(FcPN).
A.
García-Fernández, J. Gimeno, E. Lastra, C. A. Madrigal, C. Graiff,
A. Tiripicchio,
Eur.
J. Inorg. Chem.,
2007,
732-741.
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2006
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Tetra-, di- and mononuclear copper(I) complexes containing (S,S)-iPr-pybox
and (R,R)-Ph-pybox ligands.
J. Díez, M. P.
Gamasa, M. Panera,
Inorg.
Chem.,
2006,
45,
10043-10045.
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Synthesis and reactivity studies of
palladium(II) complexes containing the N-phosphorylated
iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2
(R = Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran.
V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, N. Nebra, J.
Rubio-García, Dalton Trans., 2006, 5593-5604.
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Efficient access to conjugated dienones and diene-diones from
propargylic alcohols and enolizable ketones: a tandem isomerization/condensation
process catalyzed by the sixteen-electron
allyl-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6].
V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, N. Nebra,
Adv. Synth. Catal., 2006, 348,
2125-2132.
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From alkenylphosphane aminoallenylidene
ruthenium(II) complexes to highly unsaturated
ruthenaphosphabicycloheptene complexes. J. Díez, M. P. Gamasa,
J. Gimeno, E. Lastra, A. Villar, J. Organomet.
Chem., 2006, 691, 4092-4099.
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Transfer hydrogenation of ketones catalysed by
new half-sandwich ruthenium(II) complexes bearing the sulfonated phosphane (meta-sulfonatophenyl)diphenylphosphane
potassium salt (TPPMS). J. Díez, M. P. Gamasa, E. Lastra, A. García Fernández, M. P.
Tarazona, Eur. J. Inorg. Chem., 2006,
2855-2864.
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Rhodium(III) complexes containing the ligand 2,6-bis[(4’-(S)-isopropyloxazolin-2’-yl]pyridine
((S,S)-iPr-pybox):
efficient
catalysts for asymmetric hydrosilylation of acetophenone. D.
Cuervo, M. P. Gamasa, J. Gimeno, J. Mol. Catal. A: Chem.,
2006, 249, 60-64.
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Novel carbonyliridium and -rhodium complexes
containing 2,6-bis[(4’S)-4’-isopropyloxazolin-2’-yl]pyridine
(iPr-pybox) and 2,6-bis[(4’R)-4’-phenyloxazolin-2’-yl]pyridine
(Ph-pybox) ligands. D. Cuervo, J. Díez, M. P. Gamasa, J.
Gimeno, P. Paredes, Eur. J. Inorg. Chem., 2006, 599-608.
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Synthesis of new half-sandwich
ruthenium(II) complexes bearing alkenyl- and alkynylphosphane ligands.
J. Díez, M. P. Gamasa, J. Gimeno, E. Lastra, A. Villar, Eur. J. Inorg. Chem.,
2006, 78-87.
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Catalytic isomerization of allylic
alcohols by (h6-p-cymene)-ruthenium(II)
complexes in organic and aqueous media: new recyclable and highly efficient
catalysts in water containing ammonium-functionalized
ligands. P. Crochet, J. Díez, M. A. Fernández-Zúmel, J. Gimeno,
Adv. Synth. Catal., 2006, 348,
93-100.
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2005
-
Efficient one-pot synthesis of
a,b-unsaturated
carbyne complexes fac-[RuX3{≡CC(H)=CR2}(dppf)] (X = Cl, Br; R =
aryl,
alkyl; dppf = 1,1'-bis(diphenylphosphino)ferrocene).
V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno,
Organometallics, 2005,
24, 3111-3117.
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Iminophosphorane-based
nucleophilic ruthenium(II) carbene complexes: unusual C-C coupling
and C-H activation promoted by the addition of alkynes to the Ru=C
bond. V. Cadierno, J. Díez, J.
García-Álvarez, J. Gimeno,
Organometallics, 2005, 24, 2801-2810.
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One-pot stereoselective
synthesis of organorhodium(III) complexes containing the chiral
ligand 2,6-bis[4’-(S)-isopropyloxazolin-2’-yl]pyridine (iPr-pybox).
D. Cuervo, J. Díez, M. P. Gamasa, J. Gimeno,
Organometallics, 2005, 24, 2224-2232.
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Novel (h6-arene)-ruthenium(II)
complexes containing bis(iminophosphorano)methanide and methandiide
ligands. V. Cadierno,
J. Díez, J. García-Álvarez, J. Gimeno, J. Organomet. Chem.,
2005, 690, 2087-2096.
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Novel iridium complexes containing 2,6-bis(oxazoline)pyridine
ligands: synthesis and reactivity of the diolefin iridium(I) complex
[Ir( 2-C2H4)2{ 3N,N,N-(S,S)-i-Pr-pybox}][PF6]
((S,S)-i-Pr-pybox = 2,6-bis(4'-(S)-isopropyloxazolin-2'-yl)pyridine).
J. Díez, M. P. Gamasa,
J. Gimeno, P. Paredes,
Organometallics, 2005, 24, 1799-1802.
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Intramolecular [2+2] cycloaddition of allyl C=C and allenylidene Ca=Cb
bonds: formation and deprotonation of cyclobutylidene rings.
J. Díez, M. P. Gamasa, E.
Lastra, J. Gimeno, A. Villar, Organometallics, 2005,
24, 1410-1418.
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2004
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Indenyl
ruthenium(II) aminoallenylidenes: a new building-block for the
synthesis of highly unsaturated alkynyl and allenylidene complexes.
S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, Organometallics,
2004, 23, 6299-6310.
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Base-assisted
cyclometalation and phosphorus-carbon bond cleavage in (arene)ruthenium(II) complexes containing functionalized iminophosphorane-phosphine
ligands Ph2PCH2P{=NP(=X)(OR)2}Ph2
(X = O, S; R = Et, Ph). V. Cadierno, J. Díez, J. García-Álvarez,
J. Gimeno, Organometallics, 2004, 23, 3425-3436.
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Five- and six-coordinate ruthenium(II) complexes containing the
bidentate phosphine (-)-N,N-bis(diphenylphosphino)-(S)-1-phenylethylamine
[(S)-peap]: X-ray crystal structure of the first 16 electron
ruthenium complex bearing a four membered ring [RuCl{k2-P,P-(S)-peap}2][SbF6]·C2H4Cl2.
J.
Díez, M. P.
Gamasa, J.
Gimeno,
Y.
Rodríguez,
S.
García-Granda, Eur. J.
Inorg. Chem., 2004, 2078-2085.
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Diastereoselective synthesis of the indenylruthenium(II) complexes
[Ru(h5-C9H7){k3(P,C,C)-Ph2P(CH2CR=CH2)}(PPh3)][PF6]
(R = H, Me): enantiofacial coordination, hemilabile properties, and
diastereoselective nucleophilic additions to
k3(P,C,C)-allylphosphine
ligands. P.
Álvarez, E. Lastra,
J. Gimeno, P. Braña, J. A. Sordo, J. Gómez,
L. R. Falvello,
M. Bassetti,
Organometallics, 2004, 23, 2956-2966.
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A new class of tethered-arene ruthenium(II) complexes with pendant P
and C donor atoms: synthesis of
η6:η1:η1
phosphonio-azabutadienyl ruthenabicycles via allenylidene
intermediates.
V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno,
Chem. Commun., 2004, 1820-1821.
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New chiral
ruthenium(II) catalysts containing
2,6-bis(4'-(R)-phenyloxazolin-2'-yl)pyridine (Ph-pybox) ligands for
highly enantioselective transfer hydrogenation of ketones.
D. Cuervo, M. P. Gamasa, J. Gimeno, Chem. Eur. J., 2004,
10, 425-432.
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Bis(iminophosphorano)methane derivatives as precursors of unusual
ruthenium-carbene complexes: a synthetic and DFT study.
V. Cadierno, J. Díez,
J. García-Álvarez, J. Gimeno,
Organometallics, 2004, 23, 2421-2433.
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Reaction of the ruthenium(II) indenyl complex
[Ru(h5-C9H7){k3(P,C,C)-PPh2(CH2CH=CH2)}(PPh3)][PF6]
with terminal alkynes. Mechanisms of 1-alkyne to
h1-vinylidene
transformation and kinetic detection of hemilability of the
allylphosphine ligand. M. Bassetti,
P. Álvarez, J. Gimeno, E. Lastra, Organometallics, 2004,
23, 5127-5134.
-
Efficient transfer
hydrogenation of ketones catalyzed by the bis(isocyanide)-ruthenium(II)
complexes trans,cis,cis-[RuX2(CNR)2(dppf)] (X
= Cl, Br; dppf = 1,1'-bis(diphenylphosphino)ferrocene): isolation of
active mono- and dihydride intermediates. V. Cadierno, P,
Crochet, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics,
2004, 23, 4836-4845.
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[Ru(h3-2-C3H4Me)(CO)(dppf)][SbF6]:
a mononuclear 16 e- ruthenium(II) catalyst for
propargylic substitution and isomerization of HC≡CCPh2(OH).
V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Chem.
Commun., 2004, 2716-2717.
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2003
-
An
easy entry to dimers [{RuX(m-X)(CO)(P^P)}2]
(X = Cl; Br; P^P = 1,1'-bis(diphenylphosphino)ferrocene, 1,1'-bis(diisopropylphosphino)ferrocene)
from
h3-allyl-ruthenium(II)
derivatives [RuX(h3-2-C3H4R)(CO)(P^P)]
(R = H, Me): efficient catalyst precursors in transfer hydrogenation
of ketones.
V. Cadierno, P. Crochet, J. Díez, S. E. García-Garrido, J. Gimeno,
Organometallics, 2003, 22, 5226-5234.
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Synthesis, reactivity and catalytic activity in transfer
hydrogenation of ketones of ruthenium(II) and ruthenium(IV)
complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine
ligands Ph2PCH2P{=NP(=S)(OR)2}Ph2
(R = Et, Ph).
V. Cadierno, P. Crochet, J. Díez, J. García-Álvarez, S. E.
García-Garrido, S. García-Granda, J. Gimeno, M. A. Rodriguez,
J.
Chem. Soc., Dalton Trans., 2003, 3240-3249.
-
Indenyl-ruthenium(II) allenylidene complexes containing terpenic
substituents as precursors of optically active terminal alkynes:
scope and limitation.
V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno,
J.
Chem. Soc., Dalton Trans., 2003, 3060-3066.
-
Formation of a cyclobutylidene ring: intramolecular [2+2]
cycloaddition of allyl and vinylidene C=C bonds under mild
conditions.
P.
Álvarez,
E.
Lastra, J. Gimeno, M. Bassetti, L. R. Falvello,
J. Am. Chem. Soc.,
2003, 125, 2386-2387.
-
Unexpected coupling between an
h5-indenyl
ligand and alkenylvinylidene fragments: synthesis of unprecedented (h6-indene)ruthenium(II)
metallacycles.
V. Cadierno, S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, S.
García-Granda,
Chem. Comm., 2003, 840-841.
-
Synthesis of indenyl-ruthenium(II)
s–alkynyl
complexes via nucleophilic addition of the (1R)-(+)- and
(1S)-(-)-camphor enolates on the allenylidene group of [Ru(=C=C=CPh2)(h5-C9H7)(PPh3)2][PF6]:
efficient synthesis of novel optically pure vinylidene derivatives.
V. Cadierno, M. P. Gamasa, J. Gimeno, E. Pérez-Carreño, S.
García-Granda,
J. Organomet. Chem.,
2003, 670, 75-83.
-
h5-Indenylruthenium(II)
hydride complexes: synthesis and protonation reactions.
M. P. Gamasa,
J. Gimeno, C. González-Bernardo, B. M. Martín-Vaca, J. Borge, S.
García-Granda, Inorg. Chim.
Acta, 2003, 347, 181-188.
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Novel indenyl half-sandwich osmium(II) complexes. X-ray structure of
[Os{=C=C(H)But}(h5-C9H7)(PPh3)2][PF6].OEt2.
J. Gimeno, M. González-Cueva,
E. Lastra, E. Pérez-Carreño,
S. García-Granda,
Inorg. Chim. Acta,
2003, 347, 99-106.
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Ruthenium(II) and
ruthenium(IV)
complexes
containing
k1-P-,k2-P,O-
and k3-P,N,O-iminophosphorane-phosphine
ligands
Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R
= Et, Ph):
synthesis,
reactivity,
theoretical
studies
and catalytic
activity
in transfer
hydrogenation
of cyclohexanone.
V. Cadierno, P. Crochet, J. Díez, J. García-Álvarez, S. E.
García-Garrido, J. Gimeno,
Inorg. Chem., 2003, 42, 3293-3307.
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2002
-
New ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline
(FcPN).
X-ray structures of mer,trans-[RuCl2(dppm)(FcPN)] (dppm =
bis(diphenylphosphino)methane) and cis-[RuCl2(CO)(py)(FcPN)].
J. Gimeno, E. Lastra, C. Madrigal, C. Graiff, A. Tiripicchio,
J. Organomet. Chem., 2002, 663, 204-212.
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Synthesis and properties of the indenyl ruthenium(II) complex [Ru(E)-h1-C(C≡CPh)=CHPh)(h5-C9H7)(k2-P,P-dppm)]
(dppm = bis(diphenylphoshino)methane. An organometallic intermediate
in the catalytic dimerization of phenylacetylene.
M. Bassetti,
S. Marini, J. Díez, M. P. Gamasa, J. Gimeno, Y. Rodríguez-Álvarez,
S. García-Granda, Organometallics, 2002, 21,
4815-4822.
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Catalytic
synthesis
of polynorbornene
and polynorbornadiene of
low
polydispersity
index
by [Ru(h5-C9H7)Cl(COD)]
(COD = 1,5-cyclooctadiene).
P. Álvarez,
J. Gimeno, E. Lastra,
Organometallics, 2002, 21, 5678-5680.
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Rhodium(I) and rhodium(III) complexes containing the chiral ligand
2,6-bis[4'(S)-iPr-oxazolin-2'-yl]pyridine (pybox): an
unprecedented monohapto coordination of pybox.
D. Cuervo, J.
Díez, M. P. Gamasa, S. García-Granda, J. Gimeno, Inorg. Chem.,
2002, 41, 4999-5001.
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Generation of polyunsaturated cumulene chains by unprecedented
insertions of the ynamine MeC≡CNEt2
in ruthenium(II) allenylidene complexes.
S.
Conejero, J. Díez, M. P. Gamasa, J. Gimeno, S. García-Granda, Angew. Chem.
Int. Ed., 2002, 41, 3439-3442.
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Synthesis and characterization of 2-oxacycloalkylideneruthenium(II)
complexes: X-ray crystal structure of the 2-oxacycloheptylidene
complex [Ru{=COCH2(CH2)3CH2}(h5-C9H7)(PPh3)2][PF6]·CH2Cl2.
M.
P. Gamasa, J. Gimeno, B. M. Martín-Vaca, R. Isea, A. Vegas, J.
Organomet. Chem., 2002, 651, 22-33.
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(Alkenylalkylidene)(indenyl)ruthenium(II)
complexes: synthesis by protonation of alkenyl derivatives.
K. Bieger,
J. Díez, M. P. Gamasa, J. Gimeno, M. Pavlista, Y. Rodríguez-Álvarez,
S. García-Granda, R. Santiago-García, Eur. J.
Inorg. Chem., 2002, 1647-1656.
-
Easy entry to terminal 1,5- and 1,6-enynes from (indenyl)ruthenium(II)
allenylidenes and Grignard reagents.
V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno,
Organometallics, 2002, 21, 3837-3840.
-
In search of optically active
g-keto
acetylenes via regioselective coupling of allenylidene groups and
cyclic enolates.
V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, L. R. Falvello,
R. M. Llusar,
Organometallics, 2002, 21, 3716-3726.
-
Ruthenium(II) and ruthenium(IV) complexes containing hemilabile
heterodifunctional iminophosphorane-phosphine ligands Ph2PCH2P(=NR)Ph2.
V. Cadierno, J. Díez, S. E. García-Garrido, S. García-Granda, J.
Gimeno,
J.
Chem. Soc., Dalton Trans., 2002, 1465-1472.
-
Activation of propargylic alcohols derived from hormonal steroids by
the indenyl-ruthenium(II) complex [RuCl(h5-C9H7)(PPh3)2]:
experimental and theoretical evidence of an
allenylidene-vinylvinylidene equilibrium.
V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, M. A. Rodríguez,
Organometallics, 2002, 21, 203-209.
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2001
-
Synthesis and electrochemical and theoretical studies of
Fischer-type alkenyl-carbyne tungsten complexes [(dppe)(CO)2(RNC)W{≡CCH=CCH2CH2(CH2)nCH2}][BF4]
(R = Alkyl, Aryl).
L.
Zhang, M. F. C. Guedes da Silva, M. L. Kuznetsov, M. P. Gamasa, J.
Gimeno, J. J. R. Fraústo da Silva, A. J. L. Pombeiro,
Organometallics,
2001, 20, 2782-2793.
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Octahedral ruthenium (II) complexes containing the chiral ligand
(4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline
(FcPN).
X-ray crystal structures of fac-[RuCl2(PMe3)2(FcPN)]
and fac-[RuCl2(dppm)(FcPN)] (dppm =
bis(diphenylphosphino)methane).
J.
Gimeno, E. Lastra, C. Madrigal, C. Graiff,
A. Tiripicchio,
J. Organomet. Chem., 2001, 637-639, 463-468.
-
Copper(I) complexes containing 1,1'-bis(diphenylphosphino)ferrocene
(dppf) as chelate ligand. X-ray crystal structures of [Cu2(m-Cl)2(k2-P,P-dppf)2]
and [Cu(CNtBu)2(k2-P,P-dppf)][BF4].
J.
Díez, P. Gamasa, J. Gimeno, M. Lanfranchi, A.Tiripicchio,
J. Organomet. Chem., 2001, 637-639, 677-682.
-
Synthesis and reactivity of indenyl ruthenium(II) complexes
containing the labile ligand 1,5-cyclooctadiene (COD): catalytic
activity of [Ru(h5-C9H7)Cl(COD)].
P.
Álvarez,
J. Gimeno, E. Lastra,
S. García-Granda, J. F. Van der Maelen, M. Bassetti,
Organometallics, 2001, 20, 3762-3771.
-
Reactivity of indenyl-ruthenium(II) vinylidene complexes: selective
synthesis of alkenyl-phosphonio derivatives via nucleophilic
addition of triphenylphosphine on their
h2-alkyne
tautomers.
Theoretical study of the
h1-vinylidene-h2-alkyne
tautomerization.
V. Cadierno, M. P. Gamasa, J. Gimeno, C. González-Bernardo, E.
Pérez-Carreño, S. García-Granda,
Organometallics, 2001, 20, 5177-5188.
-
Efficient synthetic routes to terminal
g–keto-alkynes
and unsaturated cyclic carbene complexes based on regio- and
diastereoselective nucleophilic additions of enolates on
ruthenium(II) indenyl allenylidenes.
V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, E. Pérez-Carreño,
S. García-Granda,
Organometallics, 2001, 20, 3175-3189.
-
Stereoselective synthesis of chiral terminal (E)-1,3-enynes derived
from the aldehydes (1R)-(-)-myrtenal and (S)-(-)-perillaldehyde
using the alkynyl-phosphonio complex [Ru{C≡CCH2(PPh3)}(h5-C9H7)(PPh3)2][PF6]
as synthon.
V. Cadierno, M. P. Gamasa, J. Gimeno,
J. Organomet. Chem., 2001, 621, 39-45.
-
Intramolecular carbon-carbon coupling reactions of a
k2(P,P)-bis(diphenylphosphino)methanide
ligand with unsaturated carbene moieties in indenyl-ruthenium(II)
complexes.
V. Cadierno, M. P. Gamasa, J. Gimeno, B. M. Martín-Vaca,
J. Organomet. Chem., 2001, 617-618, 261-268.
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2000
-
Synthesis, structural characterisation and electrochemical studies
of neutral alkenylcarbyne tungsten complexes bearing chelating
bidentate and tridentate phosphanes.
L.
Zhang, M. P. Gamasa, J. Gimeno, M. F. C. Guedes da Silva, A. J. L.
Pombeiro, C. Graiff, M. Lanfranchi, A. Tiripicchio,
Eur. J.
Inorg. Chem., 2000, 1707-1715.
-
Mono and dinuclear tungsten alkenyl-carbyne complexes bridged by
cyanide and diisocyanide ligands: synthesis, electrochemical- and
183W-NMR studies.
L. Zhang, M.
P. Gamasa, J. Gimeno, R. J. Carbajo, F. López-Ortiz, M. F. Guedes da
Silva, A. J. L. Pombeiro, Eur. J. Inorg. Chem., 2000,
341-350.
-
Nucleophilic additions of anionic Group 6 carbene complexes on
cationic indenyl-ruthenium(II) allenylidene derivatives: an easy
entry to bimetallic complexes containing
s–alkynyl-carbene
and vinylidene-carbene bridges.
V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno,
J. Chem. Soc., Dalton Trans., 2000, 451-457.
-
Dimerization of terminal alkynes catalyzed by indenyl ruthenium(II)
complexes.
M.
Bassetti, S. Marini, F. Tortorella, V. Cadierno, J. Díez, M. P.
Gamasa, J. Gimeno, J. Organomet. Chem., 2000,
593-594, 292-298.
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Reviews
-
Synthesis and reactivity of
a,b-unsaturated alkylidene and cumulenylidene group 8 half sandwich
complexes.
V. Cadierno, M. P. Gamasa, J. Gimeno,
Coord. Chem. Rev., 2004, 248, 1627-1657.
-
Recent developments in the reactivity of allenylidene and
cumulenylidene complexes.
V. Cadierno, M. P. Gamasa, J. Gimeno,
Eur. J. Inorg. Chem.,
2001, 571-591.
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Book Chapters |
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![](images/Book%2001.jpg) |
In search of asymmetric propargylic
substitution reactions mediated by optically active indenyl-ruthenium(II)
allenylidene complexes,
in
Perspectives
in Organometallic Chemistry.
Authors: V. Cadierno, S. Conejero, M. P.
Gamasa, J. Gimeno
Editorial: RSC
Editions
(Eds. C. G. Screttas, B. R. Steele)
Year: 2003
Pages:
285-296
ISBN:
0-85404-876-6
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